A two-layer model for studying 2D dissolved pollutant runoff over impermeable surfaces

Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.     

长江河口潮波传播机制及阈值效应分析

河口潮波传播过程受沿程地形(如河宽辐聚、水深变化)及上游径流等诸多因素影响,时空变化复杂。径潮动力非线性相互作用研究有利于揭示河口潮波传播的动力学机制,对河口区水资源高效开发利用具有重要指导意义。本文基于2007—2009年长江河口沿程天生港、江阴、镇江、南京、马鞍山、芜湖的逐日高、低潮位数据及大通站日均流量数据,统计分析不同河段潮波衰减率与余水位坡度随流量的变化特征,结果表明潮波衰减率绝对值与余水位坡度随流量增大并不是单调递增,而是存在一个阈值流量和区域,对应潮波衰减效应的极大值。为揭示这一阈值现象,采用一维水动力解析模型对研究河段的潮波传播过程进行模拟。结果表明,潮波传播的阈值现象主要是由于洪季上游回水作用随流量加强,余水位及水深增大,导致河口辐聚程度减小,而余水位坡度为适应河口形状变化亦有所减小,从而形成相对应的阈值流量和区域。     

岩溶山区崩滑灾害变形破坏地质模式分类

岩溶山区特殊的地质结构导致崩塌、滑坡等地质灾害时常发生，带来了严重的人员伤亡和经济社会损失。研究岩溶山区崩滑灾害特征，建立相应的变形破坏地质模式，对于岩溶山区崩滑灾害风险防控与治理工程具有重要理论意义与指导价值。文章以典型地质灾害形成演化过程为例，在系统地分析研究区典型崩滑灾害地质背景、影响因素、动力学与运动学特征的基础上，提出了岩溶山区崩滑灾害变形破坏地质模式，得出以下主要结论:（1）影响崩滑成灾基本因素（崩滑灾害体势能、岩溶结构面、岩组结构、斜坡地貌和斜坡结构）、影响因素（水文地质条件、工程活动、地震、降雨）和变形运动特征（运动形式和变形机制）三个方面，据此建立了岩溶山区崩滑灾害地质分类指标体系。（2）结合研究区特征对模型体系里面的每个要素进行系统分析，崩滑灾害的发生是各个要素相互组合、相互作用的结果。（3）总结了研究区内5种典型崩滑地质模式:高势能反倾降雨型高速远程滑坡—碎屑流模型、高势能斜倾视向采矿型高速远程崩滑灾害模型、超高势能横向陡倾地震型高速远程滑坡、高势能采矿型高速崩塌—碎屑流模型、低势能差异风化崩塌模型。为后续开展物理模拟、数值模拟、稳定性计算和变形破坏预测等工作奠定基础。下一步将更加深入全面地建立研究区的崩滑灾害模式，并进行崩滑灾害的危险性分级工作。      

烃源岩不同性质有机酸的分离及其检测方法

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。     

不同顶管组合方式的管幕冻结温度场模型试验

拱北隧道作为港珠澳大桥珠海连接线的关键性工程， 在国内外首次成功运用了管幕冻结技术。以此为背景， 为更加全面地掌握饱和软土地层中管幕冻结温度场的分布特点， 开展了不同顶管组合方式下的管幕冻结温度场模型试验研究。试验结果表明： 各测点温度曲线在积极冻结期前4 h急剧下降， 随后逐渐减缓， 降至砂土冰点后趋于平稳， 三种布管方式均满足冻结设计要求； 冻结管中低温盐水提供的冷量首先传递给顶管管壁， 再以“面”的形式均匀地传递给周围土体； 积极冻结21 h后， 采用四根空顶管组合的C区冻结壁竖向范围最大， 空管管壁正上方冻结壁平均厚度约为105 mm， 在满足管幕刚度设计要求的前提下， 可采此布管方式以达到快速形成冻结帷幕的目的。限位管开启后的4 h内， 实顶管中线垂直距离100 mm范围内测点温度曲线虽有明显回升但仍维持在冻土冰点以下， 超出此范围后温度变化影响逐渐减弱， 且顶管间冻结壁稳定存在， 表明限位管在满足管间有效封水的条件下， 能在一定范围内起到定向限制地层冻胀的作用。优化后的双圆形冻结管在满足冻结设计要求的同时， 更加便于安装且经济环保。     

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。     

Morphodynamics of an Artificial Cobble Beach in Tianquan Bay,Xiamen, China

By tracking and monitoring the profile configuration, topography, and hydrodynamic factors of an artificial cobble beach in Tianquan Bay, Xiamen, China over three consecutive years after its completion, we analyzed the evolution of its profile configuration and plane morphology, and its storm response characteristics. The evolution of the profile configuration of the artificial cobble beach in Tianquan Bay can be divided into four stages. The beach was unstable during the initial stage after the beach nourishment the profile configuration changed obviously, and an upper concave composite cobble beach formed gradually, which was characterized by a steep upper part and a gentle lower part. In the second stage, the cobble beach approached dynamic equilibrium with minor changes in the profile configuration. At the third stage the beach was in a high-energy state under the influence of Typhoon Meranti, and the response of the artificial cobble beach differed significantly from that of the low-tide terrace sandy beach. Within a short time, there was net onshore transport of cobbles in the cross-shore direction. The beach face was eroded, the beach berm was accumulated, and the slope of the beach was steepened considerably. In the alongshore direction, there was notable transport of cobbles on the beach from east to west along the shore, and the total volume of the beach decreased by 4.5×103 m~3, which accounted for 50% of the total amount of beach volume lost within three years. The fourth stage was the restoration stage after the typhoon, characterized by a little gentler profile slope and the increase in width and the decrease in height of beach berm. Because of the action of waves and the wave-driven longshore current caused by the specific terrain and landform conditions along the coast(e.g., coastal headlands, near-shore artificial structures, and reefs), the coastline of the artificial cobble beach gradually evolved from being essentially parallel to the artificial coast upon completion to a slightly curved parabolic shape, and three distinct erosion hotspots were formed on the west side of the cape and the artificial drainpipe, and the reefs. Generally, the adoption of cobbles for beach nourishment on this macro-tidal coast beach with severe erosion has yielded excellent stability and adaptability.     

海底观测网发展现状及趋势研究

文中详细研究了当前世界上最典型的海底观测网的建设发展规模、形式、设备类型以及我国海底观测网的发展现状,并对国内外海底观测网的发展趋势进行总结。对日本、加拿大、美国及欧洲的海底观测网进行了设备级研究,对我国台湾地区、东海、南海的海底观测网现状进行了研究,并讨论了国外先进观测网对我国的海底观测网建设的借鉴意义。文中总结出海底观测网发展的整体趋势为:单节点网络加速验证新型设备及传感器的水下能力;区域尺度网络用于加速多学科发展并提升灾害预警能力;而浮标平台网络作为补充,铺设在远海区域以降低阶段建设成本。     

Isolation and characterization of 49 polymorphic microsatellite loci for Decapterus maruadsi using SLAF-seq,and cross-amplification to related species

Decapterus maruadsi is a commercially important species in China, but has been heavily exploited in some areas. There is a growing need to develop microsatellites promoting its genetic research for the adequate management of this fishery resources. The recently developed specific-locus amplified fragment sequencing (SLAF-seq) is an efficient and high-resolution method for genome-wide microsatellite markers discovery. In this study, 28 905 microsatellites (mono- to hexa-nucleotide repeats) were identified using SLAF-seq technology, of which di-nucleotide was the most frequent (13 590, 47.02%), followed by mono-nucleotide (8 138, 28.15%), tri-nucleotide (5 727, 19.81%), tetra-nucleotide (1 104, 3.82%), pentanucleotide (234, 0.81%), and hexa-nucleotide (112, 0.39%). One hundred and thirty-two microsatellite loci (di- and tri-nucleotide) were randomly selected for amplification and polymorphism, of which 49 were highly polymorphic and well-resolved. The average number of alleles per locus was 13.63, ranging from 4 to 25, and allele sizes varied between 110 bp and 309 bp. The observed heterozygosity ( H_o ) and expected heterozygosity ( H_e ) ranged from 0.233 to 1.000 and from 0.374 to 0.959, with mean values of 0.738 and 0.836, respectively. The polymorphism information content (PIC) ranged from 0.341 to 0.941 (mean=0.806). However, 12 loci deviated from Hardy-Weinberg equilibrium. Furthermore, transferability tests were also successful in validating the utility of the developed markers in five phylogenetically related species of family Carangidae. A total of 48 microsatellite markers were successfully cross-amplified in Decapterus macarellus, Decapterus macrosoma, Decapterus kurroides, Trachurus japonicus, and Selaroides leptolepis. The present microsatellites provided the first known set of microsatellite DNA markers for D. maruadsi, D. macarellus, D. kurroides, and D. macrosoma, and would be useful for further population genetic and molecular phylogeny studies as well as help with the fisheries management formulation and implementation of the understudied species.

     

基于SLAF-seq技术的黑棘鲷微卫星标记开发及其在鲷科鱼类中的通用性研究

黑棘鲷(Acanthopagrusschlegelii)是广泛分布于西北太平洋的暖温性中下层经济鱼类,也是我国沿海重要的海洋捕捞鱼类和增养殖对象。然而,目前有关黑棘鲷的微卫星标记研究报道较少,难以对其种质资源状况作出精确评估。本研究采用SLAF-seq技术测序共获得22489个二至六碱基重复的黑棘鲷微卫星序列,短重复序列(二、三碱基)占总微卫星序列的90.8%,长重复序列(四至六碱基)占有9.2%。经过157对随机合成引物的多态性筛选,开发出49个高多态性的黑棘鲷微卫星标记,其中短重复序列位点有25个,长重复序列位点有24个。每个位点的等位基因数(Na)为2—20(均值为8.3),观测杂合度(Ho)和期望杂合度(He)分别为0.097—0.938和0.122—0.922(均值分别为0.663和0.701),多态信息含量(PIC)为0.118—0.897(均值为0.655)。经Bonferroni校正后,有47个位点符合哈迪-温伯格平衡(HWE),各位点间未检测到连锁不平衡现象,仅2个位点偏离HWE。结果表明,所开发的大部分微卫星标记具有高多态性,蕴含的遗传信息含量较为丰富,能够为黑棘鲷的种群遗传资源评估提供数量充足、类型多样的有效分子标记。跨物种扩增结果显示,有43个黑棘鲷微卫星标记可在9种鲷科鱼类中成功扩增,其中28个标记在太平洋棘鲷(Acanthopagruspacificus)、黄鳍棘鲷(Acanthopagruslatus)和澳洲棘鲷(Acanthopagrusaustralis)中具有较好的通用性,2个标记在平鲷(Rhabdosargussarba)、蓝点赤鲷(Pagruscaeruleostictus)、真赤鲷(Pagrusmajor)、二长棘犁齿鲷(Evynnis cardinalis)及黄牙鲷(Dentex hypselosomus)中具有通用性。这些通用性标记可为阐明鲷科属、种间的系统进化关系和棘鲷属鱼类的群体遗传学分析提供新的标记来源和研究角度。